API 571 Certification (Corrosion & Materials) Practice Test

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What is the primary factor affecting caustic corrosion in stainless steels?

  1. High temperatures

  2. Damaged passivity

  3. Alloy composition

  4. Hydrogen embrittlement

The correct answer is: Damaged passivity

The primary factor affecting caustic corrosion in stainless steels is indeed damaged passivity. Stainless steels are known for their ability to form a protective oxide layer on their surface, which is crucial for their corrosion resistance. This passive layer, primarily composed of chromium oxide, helps prevent aggressive chemicals from reaching the underlying metal. In environments where caustic substances are present, factors such as high temperatures or mechanical damage can compromise this protective film. If the passivity is damaged, the stainless steel becomes susceptible to localized corrosion attacks, leading to failures over time. The corrosive nature of caustic environments can exacerbate this issue, making it imperative to maintain a healthy passive layer to ensure the longevity and integrity of the material. While aspects like high temperatures and alloy composition may influence the overall performance of stainless steels in corrosive environments, it is specifically the damage to the passive layer that directly leads to increased susceptibility to caustic corrosion. This makes understanding and maintaining the integrity of the passive layer vital in preventing caustic corrosion in stainless steels.